Zero kinetic energy‐pulsed field ionization and resonance enhanced multiphoton ionization photoelectron spectroscopy: Ionization dynamics of Rydberg states in HBr
نویسندگان
چکیده
منابع مشابه
Zero kinetic energy-pulsed field ionization and resonance enhanced multiphoton ionization photoelectron spectroscopy: Ionization dynamics of Rydberg states in HBr
The results of rotationally resolved resonance enhanced multiphoton ionization photoelectron spectroscopy and zero kinetic energy-pulsed field ionization studies on HBr via various rotational levels of the F D2 and f D2 Rydberg states are reported. These studies lead to an accurate determination of the lowest ionization threshold as 94 098.961 cm. Observed rotational and spin–orbit branching ra...
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Sequences of pulsed electric fields have been designed and tested that enable a higher selectivity in the pulsed field ionization of high Rydberg states (n>100) than has so far been possible. The enhanced selectivity originates from the permutation of the parabolic quantum numbers n1 and n2 that is induced by a sufficiently rapid inversion of the electric field polarity during a pulse sequence....
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 1996
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.471270